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`PCT/JP2014/053873
`
`2014 46 2 A 19 A19.02.2014)
`AAR
`
`AAR
`
`(74)
`
`(81)
`
`(30)
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`(71)
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`(72)
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`(BET —A:
`$3 RA 2013-154243 2013 4£.7 A e25 A(25.07.2013)
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`JP
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`HRA: =H Gh AK S tL (MITSUI MINING
`& SMELTING CO., LID.) [JP/JP]; 71418584 RRBB
`mE AW 1 TA 11-1 Tokyo dP).
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`NL, NO, PL, PT, RO, RS, SE, SL SK, SM, TR), OAPI
`
`[iFE A|
`
`(54) Title: SULFIDE-BASED SOLID ELECTROLYTE FOR LITHIUM ION BATTERY
`
`
`
`&Intensitytau
`
`
`
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`Riess
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`(Cubic crystal, space group F-43m)
`DD Working example
`
`(57) Abstract: Provided is a solid electrolyte with which charge/discharge efficiency and cycle characteristics can be improved by
`reducing the electron conductivity of a compound which has a cubic crystal structure belonging to space group F-43m, and which is
`represented by the composition formula Li7..PS¢.,Hax (Ha being Cl or Br). This sulfide-based solid electrolyte for a lithium ion bat -
`tery is characterized by including a compound whichhasa cubic crystal structure belonging to space group F-43m, and whichis rep -
`resented by the composition formula Li7.PS¢.xHa, (Ha being Cl or Br). The sulfide-basedsolid electrolyte for the lithium ion battery
`is further characterized in that: x in the aforementioned composition formula is 0.2-1.8; and the value of the lightness (L*) thereof in
`the L*a*b* colour system is at least 60.0.
`(67) Bi:
`
`[ise A]
`
`
`
`©2015/011937Ad|INTTINITANUIMTINNIATTTTMANAANA
`
`

`

`WO2015/011937 A1 IMMTIIUTUAITANAEMIAAT AMTAMRATA
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`WO 2015/011937
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`
`PCT/JP2014/053873
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`

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`WO 2015/011937
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`PCT/JP2014/053873
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`

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`WO 2015/011937
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`

`

`WO 2015/011937
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`4
`
`PCT/JP2014/053873
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`

`

`WO 2015/011937
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`5
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`

`

`WO 2015/011937
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`WO 2015/011937
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`WO 2015/011937
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`

`

`WO 2015/011937
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`i]
`
`PCT/JP2014/053873
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`

`

`WO 2015/011937
`
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`
`PCT/JP2014/053873
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`

`WO 2015/011937
`
`11
`
`PCT/JP2014/053873
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`

`

`WO 2015/011937
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`
`PCT/JP2014/053873
`
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`

`

`WO 2015/011937
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`
`PCT/JP2014/053873
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`

`

`WO 2015/011937
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`
`PCT/JP2014/053873
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`
`

`

`WO 2015/011937
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`PCT/JP2014/053873
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`[#1]
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`

`

`WO 2015/011937
`
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`
`PCT/JP2014/053873
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`

`

`WO 2015/011937
`
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`
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`
`OD. GabmEAET FSKOl. EKSEMBIILA GCA wet F -—4 3m
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`

`

`WO 2015/011937
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`

`INTERNATIONAL SEARCH REPORT
`
`International application No.
`
`PCT/JP2014/053873
`
`A. CLASSIFICATION OF SUBJECT MATTER
`HO1M10/0562(2010.01)i, HOIB1/06(2006.01)i, HOIM10/0525(2010.01)i
`
`According to International Patent Classification (IPC) or to both national classification and IPC
`
`B.
`
`FIELDS SEARCHED
`
`Minimumdocumentation searched (classification system followed by classification symbols)
`
`HO1M10/0562, HO1B1/06, HO1M10/0525
`
`
`
`|C.DOCUMENTSCONSIDEREDTOBERELEVANTeesDOCUMENTS CONSIDERED TO BE RELEVANT
`
`Category*
`Citation of document, with indication, where appropriate, of the relevant passages
`Relevant to claim No.
`
`(Sanyo Electric Co., Ltd.
`JP 2011-96630 A
`12 May 2011 (12.05.2011),
`entire text
`& US 2011/0081580 Al
`
`
`
`
`
`R.Prasada Rao et al., Formation and
`conductivity studies of lithium argyrodite
`
`solid electrolytes using in-situ neutron
`
`
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`
`
`
`
`
` Vol.230/Issue 10, pp.72-76
`
`Documentation searched other than minimum documentation to the extent that such documents are included in the fields searched
`
`
`
`
`Jitsuyo Shinan Koho
`1922-1996
`Jitsuyo Shinan Toroku Koho
`1996-2014
`Kokai Jitsuyo Shinan Koho
`1971-2014
`Toroku Jitsuyo Shinan Koho
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`
`Electronic data base consulted during the international search (name of data base and, where practicable, search terms used)
`
`
`
`
`
`JSTPlus/JSTChina/JST7580 (JDream
`)
`
`Authorized officer
`
`
`[x] Further documents are listed in the continuation of Box C.L| See patent family annex.
`Special categories of cited documents:
`later document published after the international filing date or priority
`date and not in conflict with the application but cited to understand
`document defining the general state of the art which is not considered
`the principle or theory underlying the invention
`be of particular relevance
`earlier application or patent but published on orafter the internationalfiling
`documentof particular relevance; the claimed invention cannot be
`considered novel or cannot be considered to involve an inventive
`date
`step when the documentis taken alonc
`document which may throw doubts on priority claim(s) or which is
`ciled to establish the publication date of another citalion or other
`documentof particular relevance; the claimed invention cannot be
`special reason (as specified)
`considered to involve an inventive step when the documentis
`combined with onc or more other such documents, such combination
`documentreferring to an oral disclosure, use, exhibition or other means
`being obvious to a person skilled in the art
`document published prior to the international filing date but later than the
`document memberof the same patent family
`priority date claimed
`
`“X”
`
`to
`
`Date of the actual completion of the international search
`O09 May, 2014 (09.05.14)
`
`Date of mailing of the international search report
`20 May, 2014 (20.05.14)
`
`
`Name and mailing address of the ISA/
`
`
`
`Japanese Patent Of
`
`Form PCT/ASA/210 (second sheet) (July 2009)
`
`

`

`C (Continuation). DOCUMENTS CONSIDERED TO BE RELEVANT
`
`Citation of document, with indication, where appropriate, of the relevant passages
`
`Relevant to claim No.
`
`1-7
`
`International application No.
`
`PCT/JP2014/053873
`
` INTERNATIONAL SEARCH REPORT
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`
`
`
`Hans-Jérg Deiseroth et al., Li,PS, and Li,PS.X
`
`
`(X: Cl, Br, I): Possible Three-dimensional
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`Diffusion Pathways for Lithium Ions and
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`
`
`
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`Temperature Dependence of the Ionic
`
`Conductivity by Impedance Measurements,
`
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`
`
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`
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`Crystalline Li-Rich Solids With an Unusually
`igh Li’ Mobility, Angewandte Chemie
`
`
`International Edition, 2008.01.11, Vol.47/
`Issue 4, pp.755-758
`
`
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