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`(54) Title: SOLID-STATE BATTERY
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`(57) Abstract: One embodiment provides a solid-state battery that has a positive-electrode layer, a negative-electrode layer, and a
`lithium-ion-conducting solid electrolyte layer disposed between the positive-electrode layer and the negative-electrode layer. The
`positive-electrode layer and/or the solid electrolyte layer contains asulfide solid electrolyte, the negative-electrode layer and/or the
`solid electrolyte layer contains a solid clectrolyte comprising a hydride of a complex, and at Icast part of the sulfide solid clectrolyte
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`MATORAB A:
`EAE (WS 21 4G)
`
`

`

`WO 2015/030052
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`1
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`PCT/JP2014/072438
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`WO 2015/030052
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`WO 2015/030052
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`

`

`WO 2015/030052
`
`5
`
`PCT/JP2014/072438
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`WO 2015/030052
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`WO 2015/030052
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`7
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`PCT/JP2014/072438
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`WO 2015/030052
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`8
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`WO 2015/030052
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`9
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`PCT/JP2014/072438
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`

`WO 2015/030052
`
`10
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`

`

`WO 2015/030052
`
`11
`
`PCT/JP2014/072438
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`

`

`WO 2015/030052
`
`12
`
`PCT/JP2014/072438
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`

`

`WO 2015/030052
`
`13
`
`PCT/JP2014/072438
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`

`WO 2015/030052
`
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`
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`
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`

`WO 2015/030052
`
`15
`
`PCT/JP2014/072438
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`

`WO 2015/030052
`
`16
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`PCT/JP2014/072438
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`

`WO 2015/030052
`
`17
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`PCT/JP2014/072438
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`

`

`WO 2015/030052
`
`18
`
`PCT/JP2014/072438
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`

`

`WO 2015/030052
`
`19
`
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`isl. ZORMDLERAISAREMES CORMEMR ET SCBA 5DNS.
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`MAOVAIE (UF VASE) OAMEMRBAT STEMS,
`
`DES RAMEMBEEATSTEICKLY, QEBEOBEHABSr
`
`DBCSS. He, HEOLDICBHEMOBMAMAS SRR. RMB
`
`4 IVEBVUIR LCSD RMAC DK CREME SSRIS
`
`SCLCEMCESCHESHS,
`
`[0061]
`
`DE, 1 ~ BS RAI KS,
`
`TEMS. BSc. AaES cas Awe + OMICMBSNEV FO
`
`S1AViBSHECAT CHARBHREB* eRe,
`
`Blac lbimige ds KOUMsca ASHE BOUSTHA-AKKSMA, Hib
`
`EABMEA&SA, WicABeSE 4 UAH ASHRABOWUTHA—-AKE
`
`(hi ld. SHAK (CM ASRS eA,
`
`RUSCH ME ASME ODA< & &—BBe AECSR AK ILM ABHAO
`
`DIRS & 6 —-BBEDELTWYS
`
`SAAB WHORES NS,
`
`[0062]
`
`(SHAE ORIEAA)
`
`fu TCT. Ek LES EAB HH ORIAIAIC OW TarHAg 3.
`
`tuk LESS eBRL CRS L. SEAS ARist OM. SBORRA
`
`ABALORBDAKICOW TIA. RICRESNStEOCAAV.. PAI EA
`
`SiS PSMA WS eIARICORMS ECADU-IRKELEEDERDI—-T
`
`L—kK., AEVYVIO-hSICKY BAL, EHeHETecermkVyYURETS
`
`Aik; BRBAAVAL-TFAVTIR. AKRYIYYVAR V-P-
`
`VPIL-VaviASeAVY CRBS 4 ORB ETO RIA; Ry KALAZE
`
`KIASREZATRWI-ILDE PLAC KD CMRERBL. CHeERBLT
`
`WK FLAZKSYHS. MICMEASHASE SOAK RILME A SHS lt
`
`

`

`WO 2015/030052
`
`20
`
`PCT/JP2014/072438
`
`CHSEPHDSAWUTEDS, FLAK KDCRBELUEB LT Bere
`
`RISCoOMRICHELY. KE, EMBIS. VID TIVAS A CREST S
`
`CebpCFS,
`
`SzTheBil
`
`[0063]
`
`EAR. AER Se HPC KY RERMICERER ST SDS, AFHHONRA THIS
`
`WRESHNStEOCAAL,
`
`<I 1 >
`
`(SB ARK 3216 0 A BB A SO FS)
`
`YFIVIYVBSARFOFO-TRy7AAG LiBHs (VFILEU y FH
`
`. MHEIO%) ELI (FUE Uy Fe. HOO. 999%) &&,
`
`LiBH,z:Lil=3: 1MEMMCRSEDICAY DAAC CBALE,]
`
`Ric. BA LKEHMARABE4 SMLOSUJ—28 Ry KCKALLY S 5k
`
`SUJ—2RK-IL (@ 7mm, 2O0f8) HALT. Ky hee BEA
`
`Lk, CORY hej BMR—ILS IDB (DU vy F CHRP 7) (CRY,
`
`BaewW400rpmCS HAM XHAAIDEUYTAGY, BAKRILMEA
`
`SMA (3LiBH,z—-Lil) zx,
`
`[0064]
`
`(Bit (C0 E(k BS AB SOO Gal)
`
`FIVLIVSARFOTO-TRyI7AAG. Liss (FIVEUY FRR,
`
`HEIIO%) &PoS, (PIVEUY FRR, HEII%) He LiezS:P
`
`2S85=8 : 2DEMIEICRSKBICASY OPRMICCTBALK. Ric. BAL
`
`EMHBRBe4 SMLOVIVILTTPRyY hKRALL SSKYVIVILDP KR
`
`We (@Smm, 1608) HALT. Ky hesceicBAlA, CORY
`
`h eBRIL SLE (CD Uy FCRP 7) CRU ATI, eew5 10 Fr
`
`pmC1 26HXA-AISUYATeAYW. TLMEABHE (8OLI.2S
`
`—20P.,S.5) @8k.
`
`[0065]
`
`(TE ABB 40KO FAR )
`
`YFVALIKEY FEF (LIiOC2Hs) EXFIFNRYALEFYEIND (O
`
`CoHs) sJeRKLAELY/S—-IVICADL, WERE S BEKOWRELEA
`
`

`

`WO 2015/030052
`
`21
`
`PCT/JP2014/072438
`
`o CORRE, BHIRGPRE MABSANOLy OHRMP—O1) ICTL
`
`iCoO, (BASLE tILDY—KC-—5H) ARPL—-I-bkLE €
`
`NeBAGER. SSOCCIRMMBKLT. LiCoO,ORmIcLINb
`
`Osfk2NW1OnmvMmS t+, EMBMBCLA, Ric. BELG. EME
`
`S&S:bm ABSHEA (80LIi,5S—-20P,S,)
`
`:FyvyFrVIDyY7 (
`
`SERNA) =40:60:9f LEMKETO—-TRYIAANCHY RY,
`
`FLEAIC TIBG LT EAR BMA & LE.
`
`[0066]
`
`(SEABIO FER)
`
`bic CaaS L 7 S85 7kK (LM EASE OMRS BE 1 Omm OMKEE
`
`RBH IC AN, FHA28MP alc CHBRIC PL ARBLE (82 HASH
`
`BBORK ; LA. SAK ILMB ABHE BC bMIS) . RMBMWERY
`
`HS CeEM<, ld C Lid CHR LEME WE ABH OMAR © fe Al MIZE
`
`icCAn, BUEDA28MP all CFALARBLE (41 EKER BOM
`
`; DR. GULMEABHRERBCOMIS) . Bk. Lic CWRLiLoey
`
`ReAN, EFAZ4OMP alc C—-ARBLA. COKLIICLT. LEAR (
`
`75 um) . THUCMEASHEB (400um) SLUMAKRILMHAS
`
`MEH (400um) SIRES HNHEABKONR Ly heheh, CORLL
`
`yh OUEMBcRWIOBlk. BX¥200um, 610mmMOSBUFVUASG
`
`ABUT, SUS SO4HROBWMRRILICAN TER ALDREWec Le
`
`(FMEA)
`
`HFadD dk DICMFRLESRABHICOWT. RFYVYV ARV hSAIIN
`
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`
`YhKATBHE3. 2~4. 2V. BRHBHBO. O6 4mA/cm? (50. 8
`
`KA) ORFOK CHEBMc CHMBSTICk. BE. BBREMBE cls
`
`ENESN 3 DROIALE SRI FE,
`
`[0067] <S27e| 2 >
`
`Be9 Bl (kB AS ee IS SCR AK (LMA SHA BORBAS BOO
`
`

`

`WO 2015/030052
`
`22
`
`PCT/JP2014/072438
`
`MmMeLELAS. SHG 1 CMRICSHABSHEFPRLE. AMS
`
`DWTS. hel 1 cMRICATOK.
`
`[0068]
`
`<I 3 >
`
`fk (LYE ASHES. TLE ASHRABSLOEMBIC OWT
`
`. ZG 1 CROMER LE.
`
`(SHAS OVER)
`
`Sk (LMA SHRAOMASE BE 1 OmmMOMREAIMIBRIC AN,
`
`HA2ZSMP altlC CHBRICFLARBLE GAKFKILMEAEZHEABO
`
`FRM)
`
`. RABMERU MT CEB<. tilt CHEM EAB AaB OM RS GEA
`
`MIGHICAN, BUEA2 8SMPakCFLARBLE THELMAABHE
`
`ORM) . CONLY hOMAKRILMEABSHRABHIC. BS100u
`
`m. 68mmMO4F YVYOUASEAU TI, CZORWMICISIEMBMREAN
`
`_ EA2Z40MP alc t—-h4mB LA, COLDICUT. ERB (75 um
`
`). TULMEABREB400um, AK ILM ASHES4 OO um
`
`BKLVUAMEB7OuUm (AYVV9UABIE S$ IOmMMICBA DWE) DIRE
`
`BSnkEABKON Ly heBk. TCHESUS3O4HOB MARE ILIC
`
`ANT, SHADRBHOCLA, BE, BHORBeMMIS“e. TyUV9
`
`ASAD SLi — | nGeoBPC KS 1S.
`
`[0069]
`
`(FOIK Bah ER)
`
`FMBMRlS, Ay KA DVBEe2. O~3. CV (L i SMBH 2.
`
`62~4. 22V) &€LEWAAR 1 cle TOK.
`
`[0070]
`
`<THE4 >
`
`Bit (b POA EA BS BIS SCS ATK SS ILM ASHREABORAL BOO
`
`Meme LEW, SHGS cMRICSHABHeRLE. BWABRERIC
`
`DUTTA, SHG 1 & RICIT 2 Ze.
`
`[0071]
`
`<TH! 5 >
`
`fa VK ACME ABSHES SB. THEME ASHREBSLUEMBIC OUTS
`
`. G1 CROMER LE.
`
`

`

`WO 2015/030052
`
`23
`
`PCT/JP2014/072438
`
`(MBMARO AR)
`
`Bett. FZoa7rth (BARS CGB—-10)
`
`: HAKRILYMEA
`
`BMA (3LiBH,-Lil) :tyF¥xrv7ay7% (SHA) =27:
`
`64:9 LEMRETO-TPRYPAANCHYURY. FLAC CHALTA
`
`MBMA& Lez.
`
`[0072]
`
`(SHABHOPR)
`
`+20 CHS! LK BMBMAREA BE 1 OmmMOMRKRAIRIGHICAN, EN
`
`28MP alC CTHBRKFLARBLE (SiBORM) . MBM HY
`
`FSCOEB<. thCHAKFRICME ASHE % HAIR ICAnN, BUD
`
`28MP atl CALARBLA (GHAKRLME ASHE BORM) . Rie
`
`. TMCME ABS & tealRICAN. EA28MP alli CALAmBL
`
`Ze
`
`iiibMbASREAaBORRM) . Bic, EMBMAREAN,. EA240M
`
`Palot—-AmBLA, COKDICLT. ERB (75 um) . TibEWMeA
`
`SREB (400um) , SAKRILMEASHREAB (400um) 56k0
`
`AmB (75 um) ARB SNEABRKONLDy hee. CHeSU
`
`S304HR0BHMRLILVICANT, @HADRBHELE,.
`
`[0073]
`
`(MBAS)
`
`FMB GRIC OU Td, Ay KA VBS. 1~4. 1V (Li Bet
`
`3. 2~4. 2V) ELAN1 citFE.
`
`[0074]
`
`<I 6 >
`
`SAA 7K S16BA Se SS Beals SCHL ASHEBOBAZ8O0
`
`Meme LEELA, SHBG S & RIC PRABWHeRLE. FMRI
`
`DUTTA, SHG 1 &RICIT 2.
`
`[0075]
`
`<EE REG 1 >
`
`Sa (A 7K Sa1b A Se BS BeaSCHL AS HABORASB8OO
`
`ume LEDS. SHG 1 &ARICSAASHEFRLA. AMBRE
`
`DUTCH, SH1 cRICT OK,
`
`[0076]
`
`<BR! 2 >
`
`

`

`WO 2015/030052
`
`24
`
`PCT/JP2014/072438
`
`TEMGMBel i CoO, (AAIL4YLERAALS LER ILY—KC—
`
`5H, LiNbO,sA—bL) &L,
`
`TiEMB MAR CA SEABHE Se
`
`seazk ib (3LiBH,z-Lil) ELALA. Rieple & RIC Se
`
`ABA LK. FERRO CIA, SiG 1 cRICG OK.
`
`[0077]
`
`<EE RH 3 >
`
`EMEBICGENSEASHERSBLVEABHEBICSENS BAKED
`
`BABMESL i BHACLAWA. Shep 2 MRICS eA Bibs RL
`
`fe, FORBMBRIC OW Cld, MRR S 1 20CE LALA HSI él
`
`RRIC4T > FE.
`
`[0078]
`
`<EE RR4 >
`
`EMGMBeA-KRYI-bkSheELIFePO, (SLFP—ESO1)
`
`cL, ERMBICSENSZHABRES &teAKS(bw (SLI BH,a-Li 1)
`
`CLADAS. RAG 2 CARICSHABHEERLEA. FMBMRIC OW
`
`Tlk, AyhKAVPBEe2. 5~3. 8BVELKELMNESRHS 1 & WRIT
`
`Deo
`
`[0079]
`
`bade 1 ~6OBLULERO1~4 OBRM e., LRFORIICKELO
`
`SS, KK.
`
`IVT IVES 2041 IIVBECOMBRSOE M4 Ic
`
`RY, SCO.
`
`IVA INBEEO2 OVA IVESUVSZKERBE BH
`
`FBKOI-OVM*e, WUFOR2AIMRI. CHE. MBASld, SRL
`
`7 Bit Cis ONEKRMBR SS EMAWE lg SKU OMe LCRIGLA. B
`
`Whikild, FIBRE 1 OMBO | REFOYAFKLVYVBHWLE. 27-OvV melt
`
`_ RBAB /TREABZLVISHALE,
`
`

`

`WO 2015/030052
`
`25
`
`PCT/JP2014/072438
`
`
`
`[#21]
`
`
`“70°01|RAEICS|aS|Be|SE:Le
`
`
`BTOLNTe«Sd--S708®5%40¢-S71108“200917LApo
`
`BTOLNIN—HaneVit[1-Hane“Q09!7C1
`
`
`
`IW"Han’“Yb4064Te§$%402-S1108*$740Z-S7'108*7009"7
`
`
`
`IN"Hane“44cegIm—"Halte99%402-S*11089§740Z-S71108“20°07
`ESTQGAYI-"Hale|§§%q02-S71108's?g02-S71108“0°O!TBTOGCLIn—"Hare'%d0z-S1108“20°01“000MToL——sfin-*ane
`
`
`
`
`
`
`
`
`BTOLNInN-HaNeSoraane-S’108
`
`BSTGOLINHaneaesft-PHae“Pode
`
`TothPref____Puan"oso
`
`
`[0080]
`
`
`
`
`
`
`

`

`
`
`
`
`WO 2015/030052
`
`26
`
`PCT/JP2014/072438
`
`[#2]
`
`3ieeeCiCideSSCsSC
`
`3/yyu%%656HVG+H02|SUGSHL|BVGrH02[ENGL|OUR=|HG+402[BG41|EM#ECO—Gate
`
`
`
`
`
`SLL921
`
`PCT
`
`PT
`
`Baecz
`
`
`
`
`

`

`WO 2015/030052
`
`27
`
`PCT/JP2014/072438
`
`[0081]
`
`eae 2~4i4, MBBSens, Be UCHAEL ADO. Lid
`
`aeRO kU, AEE O RAZR IC ROSE AB ls. AMBUT AIVER
`
`YWiRLT SRM MIBALICS <. ENICHEUMEB SER LICK WCEM
`
`BOS, Ven. KEW ORMRGRICMRSSBE AB HIS. RHCDKDTR
`
`TEICEIVFARE CHSC BAS. KK. KRHMORMPRIC ROSH ABMS
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`, CRB DIVER IRLERCH 2 THI -OV OBOE FLICK We
`
`WIFREABTFSTEDBDDVE,Q
`
`SHte, ERLE KDC. AAO TEMA ICASP EAB. gaa
`
`SIGMA SIEMWEORITEMSAITSCERXK UF ULI AUVIEBSEO
`
`mo fe ATK ILM e BASH el CRAFT SCEMECES KK. SHH
`
`weeks SSRBOMCASCAMBREECLSETERRAWEO, BHEe
`
`KOVFOLTAViBRESAMES HUSTLER CES,
`
`[0082]
`
`AFH OU < DD ORMBAR = SAB LED. Choos. BEL
`
`CHELEDOCHY, SMAOMASRETSCCSRBMLTOAL., Th
`
`SPARTA IS, EOMOER ABR CRIBS NST EMABECHY,
`
`FOS SIAR LAVA C. BORK, BRA, BRAZHITC EM
`
`CXS, CHORMBBPCORGIL, FHORMAPHESICBEnNnStCEtb
`
`(Cc. SPRTER OO SGAICICRS NLA Et COWMSORAICZENS.,
`
`#75 O wiLBA
`
`[0083]
`
`1-- EMRE. 2: EABHEAB. 2a BIBABHEB. 2b B28
`
`‘ASRS. 3-- Ame.
`
`

`

`WO 2015/030052
`
`28
`
`PCT/JP2014/072438
`
`[as 5KIA1]
`
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`AUacIEMmSS tO ASHE BOUTHA—-HEKAMwAlS,
`
`PLM ABSHEAzahxa,. came S LORE ASHEBOWS
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`NA—BEK AMAIA. TAKS ABE Zea,
`
`AUact(l lAB REA ODA< & BBS AEC Te AK KIL AE
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`HE DODEA< Hb—BEDHELTWS
`
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`
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`
`Alaciel (A SAS Bld. TLV ABHE* Sd EPMO 1 AAS
`
`MER. AKA LMEASHE +e SCARWOA 2BKEHEES
`
`ce Afad SiekiR 1 CacemOPeASit.
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`Las KIR3]
`
`AAC bBABS, Li,S—-P.S.Rm. LizS-SiS,
`
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`ME SORIA 1 KKld 2 (CIRMOSEABIH.
`
`Las KIA]
`
`AUSCSe AK (LMA le, Li BHAKAIMLIBH,Z&F
`
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`
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