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`10)
`WO 2017/154922 Al
`
`HOIM 10/0562 (2010.01)
`HOIM 10/0585 (2010.01)
`
`(74)
`
`(54) Title: SOLID ELECTROLYTE, ALL-SOLID BATTERY, SOLID ELECTROLYTE MANUFACTURING METHOD AND
`ALL-SOLID BATTERY MANUFACTURING METITOD
`
`(64 HZROLM: BACHA, SHAR, AABHAORNEAARVUERABHOREGAR
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`(57) Abstract: The purpose of the present invention is to improve ionic conductivity in a solid electrolyte layer and to improvebat-
`tery charactcristics of an all-solid battcry. This solid electrolyte has a NaSICON-typecrystal structure. The solid clectrolyte is repres-
`ented by general expression Lij.Zr24,.M(PO,)3. (Part of the Li may be substituted by at least one element selected from the group
`consisting of Na, K, Rb, Cs, Ag and Ca, part of the P is may be substituted by B and/or Si, M includesat Icast one chemical clement
`which can stabilize or partially stabilize a tetragonal or cubic crystal structure of a high-temperature phase of ZrO2, and -0.50 Sa 3
`2.00, 0.01 Sb £1.90, and 0.01 Sc £1.90.)
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`WO 2017/154922
`
`1
`
`PCT/JP2017/009056
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`

`

`WO 2017/154922
`
`2
`
`PCT/JP2017/009056
`
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`

`

`WO 2017/154922
`
`3
`
`PCT/JP2017/009056
`
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`

`

`WO 2017/154922
`
`4
`
`PCT/JP2017/009056
`
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`

`

`WO 2017/154922
`
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`
`PCT/JP2017/009056
`
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`

`

`WO 2017/154922
`
`6
`
`PCT/JP2017/009056
`
`Fe, (PO,) ;3P8\%5nS. PELSAWSNEZZERIVEEZAT
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`

`

`WO 2017/154922
`
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`
`PCT/JP2017/009056
`
`[0030]
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`
`

`

`WO 2017/154922
`
`8
`
`PCT/JP2017/009056
`
`QCHSTCEMMELS. O. O1ScC251,. 7I9ICHSZCEMELY RE
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`

`

`WO 2017/154922
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`
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`
`SHICREET SC EMPCRSTRICKY BPHRELSNEBDREILVIL
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`

`

`WO 2017/154922
`
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`
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`
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`
`

`

`WO 2017/154922
`
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`
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`
`Chee1 & ltRIC L CRABB OMAEBE.
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`[0049]
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`(Se HG7 )
`
`

`

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`
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`
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`KUDSLRELYVIVIAAPeEaRLE,. COTY hYUODSARECVILIAAL
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`
`

`

`WO 2017/154922
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`
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`
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`
`

`

`WO 2017/154922
`
`14
`
`PCT/JP2017/009056
`
`KUDLRELVIVIAPZAMLE. COTY bRUDARELYILVIAP
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`Teo
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`

`

`WO 2017/154922
`
`15
`
`PCT/JP2017/009056
`
`[0066]
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`KOIMBLET EDA. LEER CBR IC LCA BREA OMRESE
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`[0068]
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`ce RACUTHUYT. Zr: YOELIEA1. O70. O3 CHET Y
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`KUDARELVIVA-~PeZAQmKlE. COTY bUDAREIEVIVIAP
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`
`

`

`WO 2017/154922
`
`16
`
`PCT/JP2017/009056
`
`Yu (Ti O2) . RRBVUFUA (Li2,CO;) .
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`UV YVROKRPYEADA
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`[0071]
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`(HG 2 4)
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`RmAGULT. BibVIVA=IDA (ZrO0,) ER bETYybKUDA (Y203)
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`cCeRBELTAUT. Zr: YDEMIEAO. 19:0. 01CHSTY
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`KUDSLRELYVIVIAAPeEaRLE,. COTY hYUODSARECVILIAAL
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`SRRCMSKDICFBLETC EDA, Lees 1 CRC LCA
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`DRA EEK.
`
`

`

`WO 2017/154922
`
`17
`
`PCT/JP2017/009056
`
`[0073]
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`(Eli B84 BO teats © ae)
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`SST, LORICSU CHRLABABHRROMRE 25°CC4. O
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`

`

`WO 2017/154922
`
`18
`
`PCT/JP2017/009056
`
`.
`
`1 ODPMYVOBRESCBRAZBSARHCS OOCOMmE THEI SC
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`CIKY, PFDS—ILABSRALKR. ZABARHEIOOOT~1 2
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`[0077]
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`Ric, HERLERES Ty KOLA ViBBEEMELA. Bewicls,
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`RisaYT7Ly KOMMCANyY SU YA cCkot, SBABCRSAS (P
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`WO 2017/154922
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`19
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`PCT/JP2017/009056
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`WO 2017/154922
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`20
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`PCT/JP2017/009056
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`WO 2017/154922
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`21
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`PCT/JP2017/009056
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`WO 2017/154922
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`22
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`PCT/JP2017/009056
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`WO 2017/154922
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`23
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`PCT/JP2017/009056
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`PCT/JP2017/009056
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`1/4
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`[B41]
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`WO 2017/154922
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`PCT/JP2017/009056
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`3/4
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`WO 2017/154922
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`PCT/JP2017/009056
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`4/4
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`

`

`INTERNATIONAL SEARCH REPORT
`
`International application No.
`
`A. CLASSIFICATION OF SUBJECT MATTER
`HO1B1/08(2006.01)i, HO1IB1/06(2006.01)i,
`(2010.01)i, HOIM10/0585(2010.01)i
`
`PCT/JP2017/009056
`
`HO1B13/00(2006.01)i,
`
`HO1M10/0562
`
`According to International Patent Classification (IPC) or to both national classification and IPC
`B.
`FIELDS SEARCHED
`
`Minimumdocumentation searched (classification system followed by classification symbols)
`
`HO1LB1/08, HO1B1/06, HO1LB13/00, HOI1M10/0562, HOI1M10/0585
`
`Documentation searched other than minimum documentation to the extent that such documents are included in the fields searched
`
`
`
`
`Jitsuyo Shinan Koho
`1922-1996
`Jitsuyo Shinan Toroku Koho
`996-2017
`Kokai Jitsuyo Shinan Koho
`1971-2017
`Toroku Jitsuyo Shinan Koho
`1994-2017
`
`Electronic data base consulted during the international search (name of data base and, where practicable, search terms used)
`
`|C.DOCUMENTSCONSIDEREDTOBERELEVANTeeeDOCUMENTS CONSIDERED TO BE RELEVANT
`
`Category*
`Citation of document, with indication, where appropriate, of the relevant passages
`Relevant to claim No.
`
`1-12
`(Murata Mf
`
`JP 2015-065022 A
`
`O09 April 2015 (09. O 2015),
`
`claims 1 to 3
`(Family: none)
`
`JP 2015-065021 A
`09 April 2015
`claims 5 to 9
`(Family: none)
`
`
`(Murata Mf
`(09.04.2015),
`
`
`
`JP 2015-065023 A
`
`
`O09 April 2015
`claims 1 to 6
`(Family: none)
`
`
`(Murata ME
`(09.04.2015),
`
`
`
`
`
`
`
`L| See patent}CZ]FurtherdocumentsarelistedinthecontinuationofBox.(]Seepatentfamivannes, annex.}CZ]FurtherdocumentsarelistedinthecontinuationofBox.(]Seepatentfamivannes,Further documents are listed in the continuation ofBox C.
`
`Authorized officer
`
`Special categories of cited documents:
`document defining the general state of the art whichis not considered
`be of particular relevance
`earlier application or patent but published on orafter the international filing
`date
`document which may throw doubts on priority claim(s) or which is
`cited to establish the publication date of anothercitation or other
`special reason (as specified)
`documentreferring to an oral disclosure, use, exhibition or other means
`document published prior to the international filing date but later than the
`priority date claimed
`
`
`